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European traders arrived in the early 16th century, beginning with the envoy of Portuguese duke Afonso de Albuquerque in 1511, followed by the French, Dutch, and English.

The Burmese–Siamese War (1765–1767) left Ayutthaya burned and sacked by King Hsinbyushin Konbaung.

The History of the Yuan mentions an embassy from the kingdom of Sukhothai in 1282.

In 1287, three Thai chiefs, Mangrai, Ngam Muang, and Ram Khamhaeng formed a "strong pact of friendship".

Ayutthaya's expansion centred along the Menam while in the northern valleys the Lanna Kingdom and other small Tai city-states ruled the area.

In 1431, the Khmer abandoned Angkor after Ayutthaya forces invaded the city.

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Ayutthaya became one of the most vibrant trading centres in Asia.

By outsiders prior to 1949, it was usually known by the exonym Siam (Thai: with the Sanskrit Śyāma (श्याम, meaning "dark" or "brown").

The names Shan and A-hom seem to be variants of the same word.

The Thai National Anthem (Thai: ), written by Luang Saranupraphan during the extremely patriotic 1930s, refers to the Thai nation as: prathet Thai (Thai: ประเทศไทย).

The first line of the national anthem is: prathet thai ruam lueat nuea chat chuea thai (Thai: There is evidence of human habitation in Thailand that has been dated at 40,000 years before the present, with stone artifacts dated to this period at Tham Lod Rockshelter in Mae Hong Son.

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